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Pain is the main antonogist of Naruto, He's the kage of his village and worshipped as a god. He has several Deva path's and controls all of them with Konan's chakra.
He formed the shady Akatsuki organization and killed several people such as Jiraiya, Kakashi Hatake, Shizune, & Tsunade Senju. He is invincble too.